Review on the effect of Iron oxides on oxygen evolution

Authors

  • Wei Zhou College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou, 311121, Zhejiang, China Author

DOI:

https://doi.org/10.63313/AERpc.2004

Keywords:

Iron oxides, electronic structure, oxygen evolution reaction

Abstract

Iron oxides exhibit significant research value and broad application potential in the oxygen evolution reaction (OER). As a crucial step in clean energy technologies such as water electrolysis and metal-air batteries, OER is constrained by sluggish reaction kinetics and high overpotential, making the development of efficient catalysts essential for improving its efficiency. Due to their abundant reserves, low cost, environmental friendliness, and tunable electronic structure, iron oxides have become a focal point in OER catalyst research. In recent years, researchers have significantly enhanced the catalytic performance and stability of iron oxides through strategies such as nanostructure optimization, doping modification, and defect engineering. This paper reviews the latest progress in OER research on iron oxides and discusses the key challenges in further improving their catalytic stability and hydrogen production efficiency.

References

[1] Abdi Z., Bagheri R., Reza Mohammadi M., et al. In Situ Synthesis of Manganese Oxide as an Oxygen-Evolving Catalyst: A New Strategy [J]. 2021, 27(4): 1330-6.

[2] Aizaz Ud Din M., Irfan S., Dar S.U., et al. Synthesis of 3D IrRuMn Sphere as a Superior Oxygen Evolution Electrocatalyst in Acidic Environment [J]. Chemistry – A European Journal, 2020, 26(25): 5662-6.

[3] Alfaruqi M.H., Mathew V., Gim J., et al. Electrochemically induced structural transformation in a γ-MnO2 cathode of a high capacity zinc-ion battery system [J]. Chemistry of Materials, 2015, 27(10): 3609-20.

[4] Priamushko T., Guggenberger P., Mautner A., et al. Enhancing OER Activity of Ni/Co Oxides via Fe/Mn Substitution within Tailored Mesoporous Frameworks [J]. ACS Applied Energy Materials, 2022, 5(11): 13385-97.

[5] Kim J., Lee J., Liu C., et al. Achieving a long-term stability by self-redox property between Fe and Mn ions in the iron-manganese spinel structured electrode in oxygen evolution reaction [J]. Applied Surface Science, 2021, 546: 149124.

[6] Wang S., Huo W., Feng H., et al. Enhancing Oxygen Evolution Reaction Performance in Prus-sian Blue Analogues: Triple-Play of Metal Exsolution, Hollow Interiors, And Anionic Regula-tion [J]. n/a(n/a): 2304494.

[7] Morales D.M., Kazakova M.A., Dieckhöfer S., et al. Trimetallic Mn-Fe-Ni Oxide Nanoparticles Supported on Multi-Walled Carbon Nanotubes as High-Performance Bifunctional ORR/OER Electrocatalyst in Alkaline Media [J]. 2020, 30(6): 1905992.

[8] Gatemala H., Kosasang S., Sawangphruk M. Bifunctional electrocatalytic CoNi-doped manga-nese oxide produced from microdumbbell manganese carbonate towards oxygen reduction and oxygen evolution reactions [J]. Sustainable Energy & Fuels, 2018, 2(6): 1170-7.

[9] Zhu S., Le J., Li J., et al. Tungsten doped manganese silicate films as stable and efficient oxygen evolution catalysts in near-neutral media [J]. Journal of Materials Chemistry A, 2021, 9(33): 17893-904.

[10] Ahmed M.G., Tay Y.F., Chi X., et al. Efficient Ternary Mn-Based Spinel Oxide with Multiple Active Sites for Oxygen Evolution Reaction Discovered via High-Throughput Screening Methods [J]. Small, 2023, 19(2): 2204520.

[11] Chen Y., Yang S., Wang T., et al. Mo-Doped α-MnO2 for Enhanced Electrocatalytic Water Oxidation [J]. ChemSusChem, 2024, n/a(n/a): e202401553-e.

[12] Deng C., Wu K.-H., Scott J., et al. Ternary MnO/CoMn alloy@N-doped graphitic composites derived from a bi-metallic pigment as bi-functional electrocatalysts [J]. Journal of Materials Chemistry A, 2019, 7(36): 20649-57.

[13] Duan Y., Huang Z., Ren J., et al. Highly efficient OER catalyst enabled by in situ generated manganese spinel on polyaniline with strong coordination [J]. Dalton Transactions, 2022, 51(23): 9116-26.

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Published

2025-03-19

How to Cite

Review on the effect of Iron oxides on oxygen evolution. (2025). Advances in Engineering Research : Possibilities and Challenges, 1(1), 65-70. https://doi.org/10.63313/AERpc.2004